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报道了一种以手性亚砜膦配体/铜络合物为催化剂的苯乙烯不对称硼胺化反应,该方法以联硼酸频哪醇酯(pin B-Bpin)和亲电性胺试剂分别作为硼源和氮源,合成手性β-氨基烷基硼酯,该产物可方便地转化为有用的手性β-羟胺类化合物.
A asymmetric boronization of styrene using chiral sulfoxide phosphine ligand / copper complex as a catalyst has been reported. This method uses pin B-Bpin and electrophilic amine reagent As a source of boron and nitrogen, a chiral β-aminoalkyl boronate ester is synthesized which is conveniently converted to a useful chiral β-hydroxylamine compound.