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在不同环境刺激下自组装形成多重胶束的“schizophrenic”嵌段共聚物由于诱人的潜在应用而引起广泛的关注。本文综述了各种刺激诱导形成多重胶束的“schizophrenic”嵌段共聚物研究情况,介绍了多重胶束化不同形态的影响因素和胶束稳定方面的进展。并对“schizophrenic”嵌段共聚物的合成与表征技巧进行了总结,最后讨论了当前研究中仍需解决的问题,并对其应用前景做了展望。
The “schizophrenic” block copolymers that self-assemble to form multiple micelles under different environmental stimuli have attracted widespread attention due to their attractive potential applications. This review summarizes the studies on the “schizophrenic” block copolymers induced by various stimuli, and discusses the influencing factors of different configurations and the progress of micellar stabilization. The synthesis and characterization techniques of “schizophrenic ” block copolymers were summarized. Finally, the problems still to be solved in the current research were discussed, and the prospect of their application was prospected.