近年来,含过氧桥双核铁络合物的研究引起了一些化学家的重视。这类络阴离子中两个高自旋的Fc(Ⅲ)通过桥氧原子的超交换作用,成了低磁性化合物,为磁化学研究提供了一个有趣的课题。人们发现,在绿色的Fe(Ⅲ)卵黄高磷蛋白(Phosritin)中含有氧桥联接的四面体配位的多核Fe(Ⅲ)原子簇。试验用化合物是将FeGl_3、吡啶、乙醇和KSCN放在高压釜中制得的。釜内充CO气体至压力为54kg/ In recent years, the study of peroxo-bridged binuclear iron complexes has attracted the attention of some chemists. The two highly-spin-like Fc (Ⅲ) in these complex anions have become low-magnetic compounds by the super-exchange of oxygen atoms in the bridge and provide an interesting topic for the study of magnetism. It has been found that tetrahedral coordinated multinuclear Fe (III) clusters with oxygen bridges are involved in the green Fe (III) Phosritin. The test compound was prepared by placing FeGl_3, pyridine, ethanol and KSCN in an autoclave. Autoclave with CO gas to a pressure of 54kg /