论文部分内容阅读
含硫席夫(Schiff)碱金属螯合物具有抗病毒,抗结核,抗肿瘤和可逆放氧活性。1-苯基-3-甲基-4-苯酰基吡唑啉酮(5)(HPMBP)金属螯合物是化学位移试剂和激光、荧光材料。因而近年来研究工作十分活跃。但Fe(Satsc H)(Satsc)(SCH)_2(SatsC H代表水杨醛缩氨基硫脲,Satsc代表Satsc H的1价阴离子)和Fe(PMBP)(L-glu)_2(PMBP代表HPMBP的1价阴离子,L-glu代表L-谷氨酸根)固态三元螯合物的工作尚未见报道。有鉴于此,我们进行了合成,并对合成的产物作了元素分析,质谱分析及红外光谱研究,确定了它们的结构:
Sulfide Schiff alkali metal chelates have antiviral, anti-TB, anti-tumor and reversible oxygen-releasing activity. 1-Phenyl-3-methyl-4-benzoylpyrazolone (5) (HPMBP) Metal chelates are chemical shift reagents and laser and fluorescent materials. In recent years, research work has been very active. However, Fe (SatscH) (Satsc) (SCH) 2 (SatsC H represents salicylaldehyde thiosemicarbazone, Satsc represents the monovalent anion of Satsc H) and Fe (PMBP) (L-glu) Monovalent anions, L-glu on behalf of L-glutamate) solid state chelate work has not been reported. In view of this, we conducted a synthesis, and the synthesis of the products were analyzed by elemental analysis and infrared spectroscopy to determine their structure: