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α-磷酸锆(α-Zr(HPO4)2·H2O,α-ZrP)、γ-磷酸锆(Zr(PO4)(H2PO4)·2H2O,γ-ZrP)及其衍生物由于在离子交换、质子传导、插层化学、催化、光化学、材料化学等领域有潜在的应用前景,因而引发了大量的研究工作。本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。
α-Zr (HPO4) 2 · H2O, α-ZrP), γ-zirconium phosphate (Zr (PO4) (H2PO4) · 2H2O, γ-ZrP) and their derivatives are widely used in ion exchange, proton conduction , Intercalation chemistry, catalysis, photochemistry, materials chemistry and other fields have potential applications, which led to a large number of research work. In this paper, the ion exchange reaction mechanism, thermodynamics and kinetics of alkali metal, alkaline earth metal and transition metal ions with zirconium phosphate and its derivatives were reviewed. The progress of ion exchange reaction between luminescent metal complexes and zirconium phosphate was also discussed.