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propose a structural angle and main refractive indices as two key factors to understand the temperature influence on the divergence angles of the Wollaston prism. The temperature influence on the divergence angles of quartz crystal Wollaston prism is studied theoretically. The results show that divergence angles decrease with increasing temperature, while the divergence angle of e-light decrease more quickly than that of o-light, The testing system is established to verify the above results, and the experimental results are in agreement well with the theoretical analysis.