【摘 要】
：
A three-dimensional coordination polymer,[Zn2(L)2(bpp)(H2O)2]n (H2L =2,5-dicarboxylic acid-3,4-ethylene dioxythiophene,bpp =1,3-di(4-pyridyl)propane),was synthe
【机 构】
：
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous
论文部分内容阅读
A three-dimensional coordination polymer,[Zn2(L)2(bpp)(H2O)2]n (H2L =2,5-dicarboxylic acid-3,4-ethylene dioxythiophene,bpp =1,3-di(4-pyridyl)propane),was synthesized with high yield under solvothermal reaction conditions and structurally characterized by elemental analysis,infrared spectra,thermogravimetric analysis,powder X-ray diffraction and single-crystal X-ray diffraction analysis.It crystallizes in orthorhombic space group Pnma with a =16.6542(9),b =18.0868(10),c =10.7528(5) (A),V=3239.0(3) (A)3,Z =4,Dc.=1.684 g/cm3,Mr =821.38,Dc.=1.684 g/cm3,μ =1.683 mm-1,F(000) =1672,R =0.0466,wR =0.0933 and S =1.066.The compound exhibits a three-dimensional structure,which can be simplified into a 2-fold interpenetratedpcu topological network.Moreover,it displays luminescence emission in the solid state at room temperature.
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