论文部分内容阅读
研究含有σ-键的过渡金属烷基配位化合物是金属有机化学中重要的课题之一,它对于了解β-消除反应机理及影响金属有机化合物的稳定性的因素具有一定的指导意义。最近我们选择了M(O)_2(R)_2(phen)(M=Mo,W)体系来研究含有σ-键的过渡金属烷基配位化合物的稳定性和结构的关系。
Studying the transition metal alkyl complexes containing σ-bond is one of the most important topics in metal-organic chemistry. It is of guiding significance for understanding the mechanism of β-elimination reaction and the factors affecting the stability of metal-organic compounds. Recently, we chose the M (O) 2 (R) 2 (phen) (M = Mo, W) system to study the relationship between the stability and the structure of the transition metal alkyl coordination compounds containing σ-bonds.