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采用激光诱导荧光技术对InCl分子 B3∏1→X1∑+荧光光谱进行了分析和归属,并对B3∏1(v’=0)→X1∑+(v"=0)的时间分辨谱进行了观测.首次得到InCl分子B2∏1态(v'=0)无碰撞辐射寿命 0≈353ns;无辐射弛豫速率常数kQ≈1.985×10-10cm3molec-1s-1及电子跃迁矩|Re|2= 0.40D2.
The fluorescence spectra of InCl molecule B3Π1 → X1Σ + were analyzed and assigned using laser-induced fluorescence. The time-resolved spectra of B3Π1 (v ’= 0) → X1Σ + (v "= 0) Observations. The first-order lifetime of collision-free radiation in the B2Π1 state (v ’= 0) of InCl molecule is 0 ≈ 353 ns. The constant of radiation-free relaxation rate kQ≈1.985 × 10-10 cm3molec-1s-1 and the electron transition moment | Re | 2 = 0.40D2.