本文研究了脱水的与水合的阳离子型沸石骨架振动的一些规律。观测到水合的单价阳离子交换的A,Y型沸石,其双环振动和变角振动的频率与阳离子晶体半径及骨架氧离子半径之和的倒数成线性关系;脱水沸石的阳离子密度及电价与A,X,Y型沸石骨架振动频率之间存在着一定的关系。此外,还考察了单价、双价与多价的水合阳离子对沸石骨架振动的影响。 In this paper, we study some regularities of the vibration of the dehydrated and hydrated cationic zeolites. It was observed that the frequencies of bicyclic vibration and angular vibration of the monovalent cation-exchanged zeolites A and Y were linear with the inverse of the sum of the cation crystal radius and the oxygen ion radius of the skeleton. The cation density and the electricity price of the dehydrated zeolite were similar to those of A, There is a certain relationship between the vibrational frequencies of X and Y zeolites. In addition, the effects of monovalent, bivalent and multivalent hydration cations on the vibration of zeolite framework were also investigated.