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One dimensional chain manganese(Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethyl-benzoic acid, 4,4’-bipyridine and manganese perchlorate anhydrous, and characterized by IR and elementary analysis. Its crystal belongs to orthorhombic space group Ccca with a=1.302 84(15) nm, b=2.601 1(3) nm, c=2.332 2(3) nm; V=7.903 5(15) nm3, Dc=1.227 g·cm-3, Z=8, F(000)=3 064, R1=0.068 4, wR2=0.210 9. The crystal structure shows that the manganese ion is coordinated with two nitrogen atoms of one 4,4’-bipyridine molecule and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 694096.
One dimensional chain manganese (Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethyl-benzoic acid, 4,4’-bipyridine and manganese perchlorate anhydrous, and characterized by IR and elementary analysis. Its crystal belongs to orthorhombic space group C = 3.322 (3) nm; V = 7.903 5 (15) nm3, Dc = 1.227 g · cm-3, and Z = 8 , F (000) = 3 064, R1 = 0.068 4, and wR2 = 0.210 9. The crystal structure shows that the manganese ion is coordinated with two nitrogen atoms of one 4,4’-bipyridine molecule and four oxygen atoms from two 2, The cyclic voltametric behavior of the complex shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 694096.