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利用DSC研究PBT/PP/PP-MAH三元共混体的结晶性质,结果表明:PP和PBT相互影响分别结晶。在PP结晶过程中,PBT起异相成核剂作用,使PP结晶速率增大,PP的Tm下降,Tc升高;而在PBT的结晶过程中,PP的熔体起稀释剂的作用,促进PBT结晶成核过程,使PBT的Tm下降,Tc升高。PP-MAH的加入,阻碍了PP大分子链向晶核的移动,同时改善了共混体的相容性。甚至在较大的PBT加入比例(28%)下,仍能促进协同效应和共同结晶。
The crystallization behavior of PBT / PP / PP-MAH ternary blend was studied by DSC. The results showed that the interaction between PP and PBT were respectively crystallized. In the process of PP crystallization, PBT acts as a heterophasic nucleating agent, increasing the crystallization rate of PP, decreasing the Tm of PP, and increasing the Tc. In the crystallization process of PBT, the melt of PP plays a role of diluent and promotes PBT crystallization nucleation process, PBT Tm decreased, Tc increased. The addition of PP-MAH hinders the movement of PP macromolecular chains to the nucleus and improves the compatibility of the blends. The synergistic effect and co-crystallization can be promoted even with larger PBT additions (28%).