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A new tripodal P,N ligand (C63H48N3O3P3) was prepared and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21/c with a = 13.013(3), b = 28.406(6), c = 14.911(3) , β = 111.04(3)o, V = 5144.6(18) 3, Z = 4, Dc = 1.276 g/cm3, Mr = 987.95, λ(MoKα) = 0.71073 , μ = 0.17 mm-1, F(000) = 2064, R = 0.0786 and wR = 0.1545. A total of 43260 unique reflections were collected, of which 5112 with I > 2σ(I) were observed. The title compound has a central benzene ring, which is linked by -NH-CO- bonds to three 2-aminophenyltriphenylphosphium moieties, of which two with P(1) and P(2) centers are pointing to the same face of the central aryl ring, while the third one directs oppositely, forming a pseudo-propeller. In the crystal structure, there exist face-to-face π-π stacking interactions which increase the stability of the crystal structure.
A new tripodal P, N ligand (C63H48N3O3P3) was prepared and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21 / c with a = 13.013 = 28.406 (6), c = 14.911 (3) β, β = 111.04 (3) o, V = 5144.6 (18) 3, Z = 4, Dc = 1.276 g / cm3, Mr = 987.95, λ (MoKα) = 0.71073 , μ = 0.17 mm-1, F (000) = 2064, R = 0.0786 and wR = 0.1545. A total of 43260 unique reflections were collected, of which 5112 with I> 2σ (I) were observed. compound has a central benzene ring, which is linked by -NH-CO-bonds to three 2-aminophenyltriphenylphosphonium moieties, of which two with P (1) and P (2) centers are pointing to the same face of the central aryl ring, while the third one directs oppositely, forming a pseudo-propeller. In the crystal structure, there exist face-to-face π-π stacking interactions which increase the stability of the crystal structure.