用于锂离子电池负极的钛酸锂/石墨烯筛复合材料制备及电化学性能

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利用微波辅助刻蚀法制备了多孔石墨烯筛(MHGO),然后通过简单的高温固相法合成了具有MHGO镶嵌的钛酸锂-多孔石墨烯筛(LTO-MHGO)复合材料.采用X射线衍射仪(XRD)、Raman光谱仪以及扫描电子显微镜(SEM)等对制备的材料进行成分分析和结构表征.结果 表明,所制备的LTO-MHGO复合材料在5 C(1 C=175 mA/g)倍率的电流密度下具有较好的循环稳定性,循环2000次后仍保持142.6mA·h/g的可逆容量.在20 C倍率的电流密度下,初次放电比容量达到170.2mA· h/g,循环500次后可逆容量仍维持在122 mA·h/g.相比于未掺杂的钛酸锂,所制备的LTO-MHGO倍率性能和长期循环性能得到大幅提升.
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