介质的碱酸度影响有机过氧化物分解速度的机理我们在实践中发现,介质的pH值会影响有机过氧化物的分解速度。例如,我们在将氯代甲酸环己酯((?)OOCCl)与过氧化钠(Na_2O_2)反应合成DCPD((?)—(?))引发剂的过程中,发现碱性物质对DCPD的分解有很明显的催化作用。当我们按正常的反应温度,在搅拌下将酸性的氯代甲酸环己酯滴加 Mechanism of the influence of the alkali acidity of the medium on the decomposition rate of organic peroxides We have found in practice that the pH of the medium affects the decomposition rate of the organic peroxide. For example, during the synthesis of DCPD ((?) - (?)) Initiator by the reaction of cyclohexyl chloroformate (OOCCl) and sodium peroxide (Na 2 O 2), we found that the decomposition of DCPD There is a clear catalytic effect. When we are at normal reaction temperature, the acidic cyclohexyl chloroformate is added dropwise with stirring