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An open-framework zincophosphate, [C4N3H16][Zn4.5(PO4)4] 1, has been hydro- thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the tetragonal space group P 4 with a = 14.512(5), c = 8.914(3), V = 1877.3(11)3,