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在盐酸体系中,以25%P204+改质剂+60%煤油为萃取有机相,酸度为40mol/L,相比O/A=005,室温条件下,测定了钪、铁、锰的分配比为DSc=2800,DFe=0312,DMn=0320;钪的萃取率为ηSc=993%,ηFe=153%,ηMn=156%.钪与铁和锰的分离系数β(Sc,Fe)=897×103,β(Sc,Mn)=875×103;萃取平衡时间为10min;考察了酸度、萃取剂浓度对萃取的影响,并用两种方法测定、绘制了萃取等温线.
In hydrochloric acid system, the organic phase was extracted with 25% P204 + modifier and 60% kerosene, the acidity was 40mol / L, compared with O / A = 005, the scandium, iron and manganese The partition ratios were DSc = 2800, DFe = 0312, DMn = 0320. The scandium extraction efficiencies were ηSc = 993%, ηFe = 153%, ηMn = 156%. The separation coefficient of scandium and iron and manganese was 897 × 103, β (Sc, Mn) = 875 × 103. The extraction equilibrium time was 10 min. The effects of acidity and extractant concentration on the extraction Influence, and measured in two ways, drawing the extraction isotherm.