【摘 要】
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The supramolecular compound [(AgI3)(4-HBPFA)2(H2O)] (Mr = 1361.11) was synthesized via the reaction of 1,1(A)-bis[(4-pyridylamino)carbonyl]ferrocene (4-BPFA) wi
【机 构】
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Department of Chemistry
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The supramolecular compound [(AgI3)(4-HBPFA)2(H2O)] (Mr = 1361.11) was synthesized via the reaction of 1,1(A)-bis[(4-pyridylamino)carbonyl]ferrocene (4-BPFA) with AgI, and structurally characterized by single-crystal X-ray diffraction analysis.Crystal data: monoclinic, space group C2/c, a = 1.6783(3), b = 10.646(2), c = 2.5419(5) (A), β = 93.66(3)o, V = 4532.2(16) (A)3, Z = 4, Dc = 1.995 g/cm3, F(000) = 2632 and μ = 3.158 mm-1.The compound consists of (4- HBPFA)+, (AgI3)2- and H2O.In the structure, the adjacent (4-HBPFA)+ are linked by C-H…O and N-H…N hydrogen bonds into 1-D chains which are further linked by C-H…I and N-H…I hydrogen bonds as well as intermolecular π-π stacking interactions to form a 3-D supramolecular compound.
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