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A new Nd(Ⅲ) coordination polymer [Nd(pidc)(H2O)4]·pidc-·7H2O(1,pidc2-= 2-py-ridyl-4,5-imidazoledicarboxylate) has been synthesized by solvothermal reaction at 120 ℃ and structurally characterized.The complex belongs to triclinic,space group P wi