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The title compound has been synthesized by the reaction of (Bu4N)2MoS4, CuCl and (C6H5CS2)(Bu4N) in DMF and recrystallized from DMF/ Et2O. The red black crystal belongs to the triclinic space group P1 with a = 12. 021 (6), b = 17.045(8), c=17. 136(7)(?) , α=110.05(3), β=108.64(4), γ=103.87 (4)°, V = 2873(3)(?)3, Dc=1. 321gcm-3, Z = 2. The structure was refined to R = 0. 065 for .4783 reflections. The anion of the title compound can be described as a MoS42- tetrahedron coordinated by two [Cu(C6H5CS2)] units with the three metal atoms lying on a line. The coordination number of each Cu atom is three.
The title compound has been synthesized by the reaction of (Bu4N) 2MoS4, CuCl and (C6H5CS2) (Bu4N) in DMF and recrystallized from DMF / Et2O. The red black crystal belongs to the triclinic space group P1 with a = 12. 021 ( A = 110.05 (3), β = 108.64 (4), γ = 103.87 (4) °, V = 2873 (3), b = 17.045 (8), c = (?) 3, Dc = 1. 321gcm-3, Z = 2. The structure was refined to R = 0.065 for .4783 reflections. The anion of the title compound can be described as a MoS42- tetrahedron coordinated by two [ Cu (C6H5CS2)] units with the three metal atoms lying on a line. The coordination number of each Cu atom is three.