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本文报道了六种含ida,edma及dien的Cu-Im-Co,Cu-Im-Pt,Co-Im-Cu-Im-Co和Co-Im-Zn-Im-Co异双核,异三核配合物的合成与表征。用~1H NMR及反射光谱证实配合物中咪唑桥的存在,并对配合物中Cu的空间构型及成键性质进行了讨论。
In this paper, we report six different heterobimetallic and heterotrimeric complexions of Cu-Im-Co, Cu-Im-Pt, Co-Im-Cu-Im-Co and Co-Im-Zn-Im- Synthesis and Characterization of Materials. 1H NMR and reflectance spectroscopy were used to confirm the existence of imidazole bridges in the complexes. The spatial configuration and bonding properties of Cu in the complexes were also discussed.