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建立了一种应用于等离子显示器(PDP)显示单元的碳纳米管(CNT)辅助电极制备工艺方法,创新性提出了场发射作为PDP平板显示的辅助性应用,并对制备的CNT辅助电极样片进行了性能评价。文章通过三维轮廓和SEM微观形貌测试手段,表征工艺过程中CNT辅助电极的宏观尺度和微观形貌。通过拉曼光谱、傅里叶红外光谱、粒径分布和ZETA电位表征与其性能直接相关的体系分散性。通过对荷电盐浓度、电泳电压、电泳时间和阴阳极板间距的系统分析和优化,获得优化电泳参数。通过关键参数对比确定了前后处理工艺及其效果。对CNT辅助电极的场发射性能进行测试,初步评价其辅助性能并考察其与PDP单元制备流程的兼容性。优化工艺制备的CNT辅助电极场发射开启电压在10μA/cm2的电流密度时低至1.2 V/μm。虽然在MgO保护层制备后增大至1.6 V/μm,但仍可保证其作为PDP辅助电极的典型功能。所建立的CNT辅助电极制备方法具备与PDP显示单元制备工艺有良好兼容性。
A method of fabricating a carbon nanotube (CNT) auxiliary electrode for a plasma display (PDP) display cell was established. Field emission was proposed as an auxiliary application of the PDP flat panel display. The CNT auxiliary electrode sample prepared was subjected to Performance evaluation. In this paper, the macro-scale and micro-morphology of the CNT auxiliary electrode during the process are characterized by three-dimensional contour and SEM micrographs. The dispersion of the system directly related to its properties was characterized by Raman spectroscopy, Fourier transform infrared spectroscopy, particle size distribution and ZETA potentials. Optimized electrophoresis parameters were obtained through systematic analysis and optimization of charged salt concentration, electrophoresis voltage, electrophoresis time and the distance between cathode and anode. By comparing the key parameters to determine the process before and after the treatment and its effect. The field emission performance of the CNT auxiliary electrode was tested to evaluate its auxiliary performance and to investigate its compatibility with the PDP unit preparation process. The CNT assisted electrode field emission turn-on voltage of the optimized process was as low as 1.2 V / μm at a current density of 10 μA / cm2. Although it is increased to 1.6 V / μm after the preparation of the MgO protective layer, it can still guarantee its typical function as a PDP auxiliary electrode. The established method for preparing the CNT auxiliary electrode has good compatibility with the preparation process of the PDP display unit.