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苝酰亚胺及其衍生物是一类具有良好的π…π堆积能力和优良的光电性能的n型半导体材料,通过该类化合物与大环化合物构筑纳米超分子组装体是近年来化学、材料科学和纳米科学等领域备受关注的研究之一。本文主要论述了近年来以共价或非共价的方法将超分子大环化合物引入到苝酰亚胺体系构筑出各种纳米功能超分子组装体的研究进展,可以认为超分子大环化合物与苝酰亚胺的组装不仅可以调节苝酰亚胺的光物理行为,而且还可以赋予超分子组装体很多新颖的物理化学特性,使其在传感材料和光电器件等方面展现出很大的潜在应用价值。这些研究极大地拓展了构筑新颖苝酰亚胺纳米超分子组装体的方法。我们相信本文对于进一步构筑具有特定结构和功能的苝酰亚胺-大环化合物超分子组装体将起到积极的促进作用。
Peryleneimides and their derivatives are a class of n-type semiconductor materials with good π ... π stacking ability and excellent optoelectronic properties. Building nanometer supramolecular assemblies from these compounds and macrocycles is a new type of material, Science and nanoscience one of the areas of concern. In this paper, we mainly discussed the recent research progress of introducing supramolecular macrocycles into peryleneimide systems by covalent or non-covalent methods to construct various nanomolecular supramolecular assemblies. It can be concluded that supramolecular macrocycles and The assembly of perylene imide can not only regulate the photophysical behavior of perylene imide, but also give many new physicochemical properties of the supramolecular assembly, presenting great potential for sensing materials and optoelectronic devices Value. These studies have greatly expanded the method of constructing novel perylene imide nanometer supramolecular assemblies. We believe this article will play a positive role in further building a peryleneimide-macrocycle supramolecular assembly with a specific structure and function.