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在Mn(OAc)_3-H_3PO_4作用下,乙酰丙酮和稠环芳烃发生反应,生成3-芳基-2,4-戊二酮。反应可能通过·CH(COCH_3)_2自由基进行的。(NH_4)_2Ce(NO_3)_6也能引起这种反应。乙酰乙酰胺及其N-甲基衍生物在Mn(OAc)_3作用下,也能发生芳基化反应。
Under the action of Mn (OAc) _3-H_3PO_4, acetylacetone reacts with PAHs to produce 3-aryl-2,4-pentanedione. The reaction may be through · CH (COCH_3) _2 radical. (NH_4) _2Ce (NO_3) _6 can also cause this reaction. Acetoacetamide and its N-methyl derivatives under the action of Mn (OAc) _3, can also occur arylation reaction.