用4-苯氧基邻苯二腈、4-(4-羟基-苯氧基)邻苯二腈、4-(β-萘氧基)邻苯二腈和无取代邻苯二腈分别和金属盐、尿素、钼酸铵在熔融状态下合成2,9,16,23-四-苯氧基金属酞菁、2,9,16,23-四-(4-羟基-苯氧基)金属酞菁和2,9,16,23-四-(β-萘氧基)金属酞菁以及无取代金属酞菁,对产物进行了IR、UV-vis光谱测定和表征,并对比3种化合物谱学性质。实验结果表明,对于芳氧基取代的金属酞菁来说,随着苯环数目和苯环上供电子基数目的增加,取代酞菁产生的红移程度都会变大。 With 4-phenoxyphthalonitrile, 4- (4-hydroxy-phenoxy) phthalonitrile, 4- (β-naphthyloxy) phthalonitrile and unsubstituted phthalonitrile and metal Salt, urea, ammonium molybdate Synthesis of 2,9,16,23-tetra-phenoxymetal phthalocyanine, 2,9,16,23-tetrakis- (4-hydroxy-phenoxy) metal phthalocyanine Cyanine, 2,9,16,23-tetrakis- (β-naphthyloxy) metal phthalocyanine and non-substituted metal phthalocyanine. The products were characterized by IR and UV-vis spectroscopy. nature. The experimental results show that for the aryloxy-substituted metal phthalocyanine, the red-shift caused by phthalocyanine substitution becomes larger as the number of benzene rings and the number of donor groups on the benzene ring increase.