【摘 要】
：
Suzuki-Miyaura catalyst-transfer polycondensation (SCTP),which proceeds following a chain-growth polymerization mechanism,has become a powerful protocol for controlled synthesis of conjugated polymers
【机 构】
：
State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chine
【出 处】
：
The 6th International Symposium on Polymer Chemistry(2014年第六
论文部分内容阅读
Suzuki-Miyaura catalyst-transfer polycondensation (SCTP),which proceeds following a chain-growth polymerization mechanism,has become a powerful protocol for controlled synthesis of conjugated polymers.1-5 However,for all the examples of SCTP,a bulky electron-donating ligand,t-Bu3P,is necessary,which results in preferable intramolecular oxidative addition over intermolecular catalyst migration,leading to a chain-growth mechanism.
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