Lithium-ion batteries (LIBs) have been attracted much attention for automobile sector. However, more research and development efforts have been focus on new materials to meet the requirement of LIBs with higher energy density and power density.[1] Graphite with a theoretical capacity of 372 m A h g-1 was considered as the commercial anode, which hindered its practical application.[3] Among various Lithium-anode materials, NiO and CoO were acted as most promising materials owing to their high theoretical capacities (716 and 718 mA h g-1).[2] Compared to pristine CoO or NiO, the NiO@CoO presented excellently enhanced conductivity.