A physical modeling system of long slim tube was established. Several pressure measuring and sampling points were laid out at different positions along the tube. Through real-time measurements of pressures and chemical concentrations at different points, the mass transfer and chemical concentration of ASP flooding in porous media are studied. The concentration of chemicals declines gradually during the fluid flow from the inlet to the outlet of the model. The concentration increases in the front edge of the slug faster than the concentration decreases in the rear edge of the slug. The concentration variation of the chemicals is an asymmetrical and offset process. The order of motion velocities of the chemicals from fast to slow is polymer, alkali and surfactant. The motion lag and comprehensive diffusion are strong in the vicinity of the inlet, the motion velocities of the chemicals are high, the difference of flow velocities among the three chemicals is significant and the chromatographic separation of the chemicals is obvious. In the area near the outlet, the comprehensive diffusion and motion lag become weak, the concentrations of the chemicals decrease, the motion velocities of the chemicals are slow, the difference among the motion velocities of the chemicals becomes small, the chromatographic separation is not obvious, the adsorption and retention of chemicals gradually increase as the chemical slug moves further along the tube, the adsorption and retention of polymer is the most serious. A physical modeling system of long slim tube was established. Several pressure measuring and sampling points were laid out in different positions along the tube. Through real-time measurements of pressures and chemical concentrations at different points, the mass transfer and chemical concentration of ASP flooding The concentration of chemicals declines gradually during the fluid flow from the inlet to the outlet of the model. The concentration of chemicals in the outlet of the slug. concentration variation of the chemicals is an asymmetrical and offset process. The order of motion velocities of the chemicals from fast to slow is polymer, alkali and surfactant. The motion lag and comprehensive diffusion are strong in the vicinity of the inlet, the motion velocities of the chemicals are high, the difference of flow velocities among the three chemicals is significant and the chromatogra the area of ​​the chemicals is slow, the difference among the motion velocities of the chemicals is small, the chromatographic separation is not obvious, the adsorption and retention of chemicals is increasing the the chemical slug moves further along the tube, the adsorption and retention of polymers is the most serious.