通过在氮杂对环吩大环分子中引入氯取代基和甲基对其进行化学修饰，成功合成新的氮杂对环吩主体化合物，并对其与萘衍生物客体２，３二羟基萘６磺酸，α萘酚，β萘酚及２，６二羟基萘包结配合行为进行研究．化学计量法表明这４种萘衍生物与主体均形成１∶１的超分子体系．研究结果发现，具有正电子荷氮杂对环吩主体不仅能识别萘衍生物的磺酸基与羟基的差异，而且还可以识别同分异构体α萘酚，β萘酚之间的差异，表明了主客体间的静电引力、分子结构、几何互补在分子受体选择性键合底物形成超分子体系的重要作用 By introducing chlorine substituents and methyl groups into the azaheterocyclic ring macrocycles, the new aza-heterocyclic ring compounds were successfully synthesized, and their intermediates were successfully synthesized with 2,3-dihydroxy Naphthalene  6 sulfonic acid, α  naphthol, β  naphthol and 2,6  dihydroxynaphthalene inclusion complex behavior. Stoichiometry showed that these four naphthalene derivatives and the host form a 1: 1 supramolecular system. The results showed that positronium-donating aza-heterocyclic ring-like host can not only identify the difference between the sulfonic acid group and the hydroxyl group of the naphthalene derivatives, but also identify the differences between the isomers of α-naphthol and β-naphthol The difference indicates the electrostatic attraction between host and guest, the molecular structure, and the important role of geometric complementation in the formation of supramolecular systems by the selective bonding of substrates by molecular acceptors