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Cp<sub>2</sub>ZrCl(S<sub>2</sub>CNBz<sub>2</sub>) is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549(1)A; Zr-C 2.489-2.533; Zr-S 2.667(1), 2.734(1); Zr-Cl-S1 13