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A new inorganic-organic hybrid framework microporous material Cd 3(BDC) 0.5(BTC) 2·(DMF)(H 2O)·3DMF·H 3O·H 2O, in which two kinds of carboxylate ligands coordinate with cadmium ions synchronously, was obtained under a mild synthesis condition. The titled compound is crystallized in a monoclinic system, space group P2(1)/c with a=1.584 7(7) nm, b=1.426 7(6) nm, c=1.936 3(6) nm, β=113.186(7)°, V=4.024 6(3) nm 3, Z=4, D X=1.947 mg/m 3, M r=1 179.92, μ=1.662 mm -1, F(000)=2 344, R=0.074 8, wR=0.215 1. Three cadmium centers link with each other through BDC or BTC ligand to form a 3-D open framework.
A new inorganic-organic hybrid microporous material Cd (BDC) 0.5 (BTC) 2 · (DMF) (H 2 O) · 3DMF · H 3O · H 2O, in which two kinds of carboxylate ligands coordinate with cadmium ion synchronously, was The titled compound is crystallized in a monoclinic system with space group P2 (1) / c with a = 1.584 7 (7) nm, b = 1.426 7 (6) nm, c = ), β = 113.186 (7) °, V = 4.024 6 (3) nm 3, Z = 4, DX = 1.947 mg / m 3, M r = 1 179.92, μ = 1.662 mm -1, F (000) = 2 344, R = 0.074 8, wR = 0.215 1. Three cadmium centers link with each other through BDC or BTC ligand to form a 3-D open framework.