论文部分内容阅读
本文论述了[2_s+n_a]有C_2对称性,而m>2的[m_s+n_a]由HMO模型得到的分子轨道的特殊对称性是过分简化造成的。这种简化可认为是把m_s组分的碳骨架看成直线,因而可安排成C_2对称性。按照分子轨道的特殊对称性容易构成相关图。本文还论证了[m_s+m_a]全部分子轨道的二重简并性。
This paper deals with the fact that [2_s + n_a] has C_2 symmetry, and [m_s + n_a] of m> 2 is caused by the over-simplification of the special symmetry of the molecular orbitals obtained by the HMO model. This simplification can be considered as the carbon skeleton of the m_s component as a straight line, which can be arranged into C_2 symmetry. In accordance with the special symmetry of the molecular orbit easily constitute the relevant map. The paper also demonstrates the dual degeneracy of all molecular orbitals of [m_s + m_a].