与有机和无机氟化学(从1670年开始)相比,氟聚合物的历史是相当短的。最早的氟聚合物是20世纪30年代末期合成的低相对分子质量的聚三氟氯乙烯(PCTFE),之后在1938年由Plun-kett首次合成了聚四氟乙烯(PTFE)。随后又合成了不同氟单体的均聚物或共聚物。今天,不同功能的聚合物具有独 The history of fluoropolymers is quite short compared to organic and inorganic fluorochemistry (since 1670). The earliest fluoropolymers were low-molecular-weight polychlorotrifluoroethylene (PCTFE), synthesized in the late 1930s, and polytetrafluoroethylene (PTFE) was first synthesized in 1938 by Plun-kett. Subsequently, homopolymers or copolymers of different fluoromonomers were synthesized. Today, different functional polymers have their own uniqueness