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A new sulfate inorganic framework, {(C2H8N)9[Nd5(SO4)12]·2H2O}n(1) templated by organic amine, has been solvothermally synthesized and characterized by TGA, PXRD and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group C2/c with a = 20.570(5), b = 35.815(8), c = 10.106(2) , C318H72N9Nd5O50S12, Mr = 2315.73, V = 6765(3) , Z = 4, Dc = 2.274 g·cm-3, μ = 4.253 mm-1, F(000) = 4520, 2.52<θ<25°, λ(MoKα) = 0.71073 , T = 273(2) K, the final R = 0.0401, wR = 0.1022 and S = 1.042. X-ray diffraction analysis reveals that complex 1 possesses a 3D inorganic sulfate framework with large 20-membered ring(20 MR) and 10-membered ring(10 MR) channels constructed by two kinds of SBUs. Moreover, the UV-vis and luminescent properties of complex 1 were also investigated.
A new sulfate inorganic framework, {(C2H8N) 9 [Nd5 (SO4) 12] · 2H2O} n (1) templated by organic amine, has been solvothermally synthesized and characterized by TGA, PXRD and single-crystal X-ray diffraction 1 crystalizes in monoclinic space group C2 / c with a = 20.570 (5), b = 35.815 (8), c = 10.106 (2), C318H72N9Nd5O50S12, Mr = 2315.73, V = 6765 (3), Z = 4, Dc = 2.274 g · cm -3, μ = 4.253 mm -1, F (000) = 4520, 2.52 <θ <25 °, λ (MoKα) = 0.71073, T = 273 (2) K, the final R = wR = 0.1022 and S = 1.042. X-ray diffraction analysis reveals that complex 1 possesses a 3D inorganic sulfate framework with large 20-membered ring (20 MR) and 10-membered ring (10 MR) channels constructed by two kinds of SBUs. Moreover, the UV-vis and luminescent properties of complex 1 were also investigated.