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环己烯基-2-烯丙基锌经金属-克兰荪重排反应,生成2-烯丙基-1,1-偕二金属环己烷。通过对温度、溶剂量和投料顺序等重排反应主要影响因素的考察,可使2-烯丙基1,1-偕二金属环己烷的收率达到65％。
Cyclohexenyl-2-allylzinc undergoes a metal-Clarn-Sun rearrangement reaction to produce 2-allyl-1,1-gem-di-metallic cyclohexane. Through the investigation of the main influencing factors of the rearrangement reaction such as temperature, solvent amount and feeding sequence, the yield of 2-allyl 1,1-gem metalcyclohexane can reach 65%.