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Galvanic compatibility between graphite epoxy composite materials (GECM) andLY12CZ aluminum alloy was evaluated in different atmospheric corrosion environ-ments and by laboratory electrochemical measurements. Open circuit potential elec-trochemical measurements showed a relatively large potential difference about 1 voltbetween the GECM and LY12CZ aluminum alloy, and this difference provided thedriving force for galvanic corrosion of the LY12CZ aluminum alloy as an anode.Having been exposed for 1, 3 or 5 years in Beijing, Tuandao and Wanning station,GECM/L Y12CZ couples showed significant losses of strength and elongation. Protec-tive coatings and non-conductive barriers breaking the galvanic corrosion circuit wereevaluated under the same atmospheric corrosive conditions. Epoxy primer paint, glasscloth barriers and LY12CZ anodizing were effective in galvanic corrosion control forGECM/L Y12CZ couples.