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本文通过理论计算与实验测试,证明在溶液中 Hg_2O 发生歧化反应,生成 HgO 与 Hg;Hg_2I_2不发生歧化反应,只有在 KI 过量时,由于生成更稳定的[HgI_4]~(2-)才发生歧化反应。
In this paper, theoretical calculations and experimental tests show that the Hg_2O disproportionation reaction in solution produces HgO and Hg; Hg_2I_2 does not disproportionation reaction, only in the KI excess, due to the formation of more stable [HgI_4] ~ (2-) disproportionation reaction.