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本文对现有中,高温固相化学反应方法合成含硫原子簇化合物作了探讨,介绍了我们实验室用低热温度固相反应合成原子簇化合物的新方法,总结了几年来我们用此法合成的S-Mo(W)-Cu(Ag)原了簇化合物,并测定结构二十余个,其中包括了含有二十个金属原子的大核原子簇化合物[(n-Bu)_4N]_4[Mo_8Cu_(12)S_(32)]。
In this paper, the existing intermediate and high temperature solid-phase chemical synthesis of sulfur atom-containing cluster compounds are discussed, introduced our laboratory with low temperature solid-state reaction synthesis of cluster compounds a new method, summarized in a few years we use this method synthesis S-Mo (W) -Cu (Ag) clusters were synthesized and more than 20 structures were determined, including the large nuclear clusters containing 20 metal atoms [(n-Bu) _4N] _4 [ Mo_8Cu_ (12) S_ (32)].