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以2-[N,N-二(2-吡啶甲基)氨甲基]-6-醛基-4-甲基苯酚(L)为配体,合成了2个单核铜配合物[CuL(CH3CN)(ClO4)]ClO4(1)和cis-[CuL(NCS)2]·0.5C4H8O2(2),对它们进行了紫外、红外、质谱、元素分析和单晶结构表征。2个配合物都属于单斜晶系,每个铜均为扭曲的八面体构型。作为四齿配体,L通过2个吡啶氮原子,1个叔胺氮原子和1个酚氧原子和铜离子配位。在配合物1中,乙腈和1个ClO4-参与配位,而在配合物2中2个硫氰根离子为顺式配位。
Two mononuclear copper complexes [CuL (2-pyridylmethyl) aminomethyl] -6-aldehyde-4-methylphenol (L) (ClO4)] ClO4 (1) and cis- [CuL (NCS) 2] · 0.5C4H8O2 (2) were synthesized and characterized by UV, IR, MS, elemental analysis and single crystal structure. Both complexes belong to the monoclinic system, each of which is a distorted octahedron. As a tetradentate ligand, L is coordinated with copper ions by two pyridine nitrogen atoms, one tertiary amine nitrogen atom and one phenolic oxygen atom. In complex 1, acetonitrile and 1 ClO4- participate in the coordination, while in complex 2 2 thiocyanate ions are cis-coordinated.