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Under solvothermal conditions, a new Zn(Ⅱ) coordination polymer, namely [(CH3)2NH]2[Zn(bpea)(bib)]·2H2O(1, H2 bpea = biphenylethene-4,4?-dicarboxylate and bib = 1,4-bis(1-imidazolyl) benzene), has been synthesized with mixed organic ligands. Complex