【摘 要】
：
Pillar[5]arenes,designed and prepared by Ogoshi et al.in 2008 initially,refer to fifth classical macro-cyclics.Among a wide range of pillar[5]arenes,rim-differentiated pillar[5]arenes containing five iden-tical substituents on one rim and five different i
【机 构】
：
Department of Chemistry,Changzhi University,Changzhi 046011,China;School of Chemistry and Chemical E
论文部分内容阅读
Pillar[5]arenes,designed and prepared by Ogoshi et al.in 2008 initially,refer to fifth classical macro-cyclics.Among a wide range of pillar[5]arenes,rim-differentiated pillar[5]arenes containing five iden-tical substituents on one rim and five different identical groups on the other rims are considered the most noteworthy type of pillar[5]arenes.As compared with the perfunctionalized pillar[5]arene,the self-assembly properties of rim-differentiated pillar[5]arenes have more varieties.On the other hand,in comparison with other types of pillar[5]arenes,the rim-differentiated pillar[5]arenes exhibit a more rigid symmetrical structure.In the present review,the synthetic methods,host-guest interactions,self-assembly properties and applications of rim-differentiated pillar[5]arenes are summarized.Hopefully,this review will be conducive to researchers in macrocyclic supramolecular chemistry.
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