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The title compound (C4N2H12)2Zr(C2O4)4.H2O 1 was synthesized by the reaction of ZrOCl2.8H2O, H2C2O4.2H2O and piperazinium in aqueous solution. Single-crystal X-ray analysis has revealed that compound 1 (C16H26N4O17Zr, Mr=637.63) crystallizes in the monocl