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综述了在电场下由绝缘态(“0”态)到导电态(“1”态)的电开关记忆特性的几类化合物薄膜,包括聚苯乙烯及其衍生物的辉光放电聚合膜,酞青铅和TCNQ(7,7,8,8-四氰基对苯酸二甲烷)及其衍生物的电荷转移复合物的真空蒸发膜.乙酰丙团铜的弧光放电等离子体聚合膜,1,3-二硫杂环戊烯-乙硫醇(dmit)类过渡金属配合物的电沉积膜,含大共轭п键有机化合物及偶氨化合物与TCNQ的电荷转移复合物的Lansmuir-Blodgett(LB)膜,以及用离子团束-飞行时间质谱仪制备的C60-TCNQ和Ag-TDCN(TDCN为多共轭苯腈)薄膜。
Several types of compound thin films, including glow discharge polymerized films of polystyrene and its derivatives, phthalocyanine derivatives, are reported in the electric field under the electric state of the switch (“0” state) to the conductive state Vacuum evaporation of charge-transfer complexes of lead and TCNQ (7,7,8,8-Tetracyano-p-toluate) and their derivatives. Arc discharge plasma polymerization film of copper acetylacetonate, electrodeposition film of 1,3-dithiol-ethanethiol (dmit) -type transition metal complex, organic compound containing a large conjugated y-bond and diamine Lansmuir-Blodgett (LB) membranes of charge-transfer complexes of compounds with TCNQ, and C60-TCNQ and Ag-TDCN (TDCN polycondensation cyanide) membranes prepared by ion beam-time of flight mass spectrometry.