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标题化合物{[Ag-(C2H8N2)](C7H4NO4)·H2O}n中,银原子分别与两个乙二胺中的一个N原子配位,在a轴方向形成[ Ag N C C N ]n一维链,这些线型的链通过N-H…O和O-H…O等氢键的作用,连接构成与ab平面平行的二维网,形成二维平面结构.通过研究配体和配合物的红外光谱进一步确定了标题配合物的结构.
In the title compound {[Ag- (C2H8N2)] (C7H4NO4) · H2O} n, the silver atom is coordinated with one N atom of two ethylenediamine respectively to form [Ag NCCN] n one- These linear chains are connected by a hydrogen bond, such as NH ... O and OH ... O, to form a two-dimensional network parallel to the ab plane to form a two-dimensional planar structure. The infrared spectra of the ligand and the complex further confirm the title Structure of complex.