【摘 要】
:
The polyoxometalate(CPFX·HCl)3 H3 PW12 O40 ·8H2 O was prepared and characterized by elemental analysis,IR spectra and TG-DTA-DTG.The thermal decomposition mec
【机 构】
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Hubei Key Laboratory of Bioanalytical Technique Department of Chemistry and Environmental Engineerin
【出 处】
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Journal of Wuhan University of Technology(Materials Science
论文部分内容阅读
The polyoxometalate(CPFX·HCl)3 H3 PW12 O40 ·8H2 O was prepared and characterized by elemental analysis,IR spectra and TG-DTA-DTG.The thermal decomposition mechanism and non-isothermal kinetic parameters of the polyoxometalate were obtained from the analysis of TG-DTG data using the Achar equation,Coats-Redfern equation(CR),Madhusudanan-Krishnan-Ninan equation(MKN)and Horowitz-Metzger equation(HM).And their mathematical expressions of the kinetic compensation effect were also calculated.
The polyoxometalate (CPFX · HCl) 3 H3 PW12 O40 · 8H2 O was prepared and characterized by elemental analysis, IR spectra and TG-DTA-DTG. The thermal decomposition mechanism and non-isothermal kinetic parameters of the polyoxometalate were obtained from the analysis of TG-DTG data using the Achar equation, Coats-Redfern equation (CR), Madhusudanan-Krishnan-Ninan equation (MKN) and Horowitz- Metzger equation (HM) .And their mathematical expressions of the kinetic compensation effect were also calculated.
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