曾使用过各种方法来把具有防老剂性能的化学结合的酚类或胺类取代物引入聚二烯分子。有效的防老剂基团,如3,5-二-特丁基-4-羟基苯基和4-苯胺基苯胺基基基团,在自由基聚合过程中通过使用由这类官能团取代的丙烯酸共聚用单体引进了聚二烯。Kline和Mjller评述过在二次聚合时使胺基-,羟基-或亚硝基取代的化合物与已存在于聚二烯基质中 Various methods have been used to introduce chemically bound phenolic or amine substituents with antioxidant properties into polydiene molecules. Effective antioxidant groups, such as 3,5-di-tert-butyl-4-hydroxyphenyl and 4-anilinoanilino groups, are obtained during free-radical polymerization by the use of acrylic acid copolymerized by such functional groups Polydiene was introduced with the monomer. Kline and Mjller reviewed that compounds that are amine-, hydroxy- or nitroso-substituted in the second polymerization react with compounds already present in the polydiene matrix