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本文按球堆集模型的八面体和四面体模式分别讨论了4n+2和4n’电子数分类的反应机制问题,发现这两种模式分类可推广至原认为非周环的协同机制和离子型反应。对奇数电子体系可按4n+1和4n+3电子数分类,它概括了游离基、基式离子及单电子的氧化还原过程。这样,可统一为4n+m(m=0,1,2,3)的反应电子数分类方案。并就各主要有机化学反应类型作了列表分类,同时也对各类反应物种(包括有关无机试剂)作了列表分类。按各分类举例作了简要说明,在此过程中,指出了4n+2、4n+3的组合较为稳定,这两类物种较为惰性,而4n,4n+1则相反的事实。对4n+1、4n+3两类物种活性差异,给予了一种数理方面的解释。
In this paper, we discuss the reaction mechanism of 4n + 2 and 4n ’electronic number classification according to the octahedron and tetrahedron model of the ballistic model. We find that these two models can be generalized to the original synergistic mechanism and ionic reaction . For odd-numbered electronic systems, 4n + 1 and 4n + 3 electrons are classified, which summarizes the redox processes of radicals, radicals and single electrons. In this way, we can unify the 4n + m (m = 0,1,2,3) reaction electron number classification scheme. A list of the major types of organic chemical reactions is also included in the list, as well as a list of types of reactive species (including inorganic reagents). A brief description of each classification is given. In the process, it is pointed out that the combination of 4n + 2,4n + 3 is relatively stable, the two species are relatively inert, and the fact that 4n and 4n + 1 are the opposite. On the 4n +1, 4n +3 two types of species activity differences, given a mathematical explanation.