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In this paper, we calculate the branching ratios and the direct CP-violating asymmetries for decays B0 →a00(980)π0, a0+(980)π-, a0-(980)π and B- →a00(980)π-, a0-(980)π0 by employing the perturbative QCD (pQCD) factorization approach at the leading order. We found that (a) the pQCD predictions for the branching ratios are around (0.4 - 2.8) × 10-6, consistent with currently available experimental upper limits; (b) the CP asymmetries of B0→ao(980)π0 and B-→a0-(980)π0 decays can be large, about (70-80)% for α = 100°.