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本文合成了β-氯乙基缩水甘油醚及其聚合物.结果表明,AIEt_3-0.5H_2O体系是β-氯乙基缩水甘油醚的一种有效的聚合引发剂.研究了聚(β-氯乙基缩水甘油醚)的酯化反应动力学,并通过~1H NMR和IR光谱确立了酯化度的计算关系式.最后,通过光交联的动力学研究发现,酯化聚合物中的肉桂酰基含量为85%时,材料的感光灵敏度最高
In this paper, β-chloroethyl glycidyl ether and its polymer were synthesized.The results showed that AIEt_3-0.5H_2O system is an effective polymerization initiator of β-chloroethyl glycidyl ether.Studies on the effect of poly Ester glycidyl ether) esterification reaction kinetics, and ~ 1H NMR and IR spectra established the calculation of the relationship between the degree of esterification.Finally, through the kinetics of photocrosslinking study found that esterified polymer cinnamoyl When the content is 85%, the sensitivity of the material is the highest