【摘 要】
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The N-heterocyclic carbene (NHC)-catalyzed reactions involving two-electron reaction pathway have been well-established.However,the development of NHC-catalyzed
【机 构】
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Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and
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The N-heterocyclic carbene (NHC)-catalyzed reactions involving two-electron reaction pathway have been well-established.However,the development of NHC-catalyzed radical reactions is still in its infancy in terms of reaction types and enantioselectivity.In the past decade,several elegant NHC-catalyzed radical reactions have been developed,including NHC-catalyzed oxidation of aldehydes to esters,reductive coupling reactions using Breslow intermediate as SET reductant and NHC-catalyzed reactions via radical homoenolates,dienoaltes and trienolates.This review summarizes the recent advances in NHC-catalyzed reactions involving radical intermediates.
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